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Sanmartinite

A valid IMA mineral species - grandfathered
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About SanmartiniteHide

Formula:
(Zn,Fe)WO4
Colour:
Reddish brown; dark brown to brownish black (massive)
Lustre:
Resinous
Hardness:
4 - 4½
Specific Gravity:
6.7
Crystal System:
Monoclinic
Name:
Named for Department of San Martín in the Province of San Luis, Argentina. The region, the type locality for the mineral, is in turn named for 'the great liberator General José de San Martín.'
Wolframite Group.
An uncommon secondary mineral resulting from the alteration of scheelite.


Unique IdentifiersHide

Mindat ID:
3523
Long-form identifier:
mindat:1:1:3523:7
GUID
(UUID V4):
58d4d13f-e6af-4ec3-a128-bb765c31c8d8

IMA Classification of SanmartiniteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Zn(WO4)
First published:
1948

Classification of SanmartiniteHide

4.DB.30

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra
48.1.1.3

48 : ANHYDROUS MOLYBDATES AND TUNGSTATES
1 : AXO4

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
SmaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of SanmartiniteHide

Resinous
Transparency:
Translucent
Colour:
Reddish brown; dark brown to brownish black (massive)
Comment:
Dark red internal reflections.
Hardness:
4 - 4½ on Mohs scale
Cleavage:
Perfect
On {010}, perfect.
Density:
6.7 g/cm3 (Measured)    7.87 g/cm3 (Calculated)
Comment:
Calculated density value based on synthetic ZnWO4.

Optical Data of SanmartiniteHide

Type:
Biaxial (+)
Dispersion:
relatively strong

Chemistry of SanmartiniteHide

Mindat Formula:
(Zn,Fe)WO4
Common Impurities:
Ca,Mn

Crystallography of SanmartiniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Cell Parameters:
a = 4.702 Å, b = 5.726 Å, c = 4.948 Å
β = 90.3°
Ratio:
a:b:c = 0.821 : 1 : 0.864
Unit Cell V:
133.22 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals rare and minute, only to 60 μm, tabular on {001}, with {001}, {010}, {110}, {112}, and {102}. Commonly in reticulated aggregates and fine-grained massive.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006599SanmartiniteRedfern S A T, Bell A M T, Henderson M B, Schofield P F (1995) Rietveld study of the structural phase transition in the sanmartinite (ZnWO4)- cuproscheelite (CuWO4) solid solution European Journal of Mineralogy 7 1019-102819950293
0006600SanmartiniteRedfern S A T, Bell A M T, Henderson M B, Schofield P F (1995) Rietveld study of the structural phase transition in the sanmartinite (ZnWO4)- cuproscheelite (CuWO4) solid solution European Journal of Mineralogy 7 1019-102819950293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.931 Å(100)
2.908 Å(90)
3.73 Å(40)
4.69 Å(35)
3.62 Å(35)
2.472 Å(35)
2.464 Å(35)
Comments:
Synthetic. The data are from Swanson et al. (1963).

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of SanmartiniteHide

General Appearance of Type Material:
Fine granular masses.
Place of Conservation of Type Material:
The Natural History Museum, London, England: 1978,353.
The Academy of Natural Sciences, Philadelphia, USA: #25575.
Harvard University, Cambridge, Massachusetts, USA: #134566.
U.S. National Museum of Natural History, Washington, D.C., USA: #105681, 137479.
Geological Setting of Type Material:
Quartz vein between granite and granitic pegmatite intruding Precambrian crystalline schists.
Associated Minerals at Type Locality:
Reference:
Angelelli, V., Gordon, S.G. (1948) Sanmartinite, a new zinc tungstate from Argentina. Notulae Naturae of The Academy of Natural Sciences of Philadelphia: 205: 1-7.

Synonyms of SanmartiniteHide

Other Language Names for SanmartiniteHide

Relationship of Sanmartinite to other SpeciesHide

Other Members of this group:
DmitryvarlamoviteTi2(Fe3+Nb)O8Orth. 2 2 2 : P21 21 2
FerberiteFeWO4Mon. 2/m : P2/b
HeftetjerniteScTaO4Mon. 2/m : P2/b
HuanzalaiteMgWO4Mon. 2/m : P2/b
HübneriteMnWO4Mon. 2/m : P2/b
KrasnoselskiteCoWO4Mon.
NioboheftetjerniteScNbO4Mon. 2/m : P21/b
Rossovskyite(Fe3+,Ta)(Nb,Ti)O4Mon. 2/m : P2/b

Related Minerals - Strunz-mindat GroupingHide

4.DB.NioboheftetjerniteScNbO4Mon. 2/m : P21/b
4.DB.Shakhdaraite-(Y)ScYNb2O8Mon. 2/m : P2/b
4.DB.Nioboixiolite-(Mn2+)(Nb0.67Mn2+0.33)O2Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.Nioboixiolite-([])(Nb0.80.2)4+O2Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.05ArgutiteGeO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05CassiteriteSnO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05PlattneritePbO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05PyrolusiteMn4+O2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05RutileTiO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05TripuhyiteFe3+Sb5+O4Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05TugarinoviteMoO2Mon. 2/m : P21/b
4.DB.05Varlamoffite(Sn,Fe)(O,OH)2
4.DB.10ByströmiteMgSb2O6Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm
4.DB.10Tapiolite-(Fe)Fe2+Ta2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.10Tapiolite-(Mn)Mn2+Ta2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.10OrdoñeziteZnSb2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.10TredouxiteNiSb2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.15bAkhtenskiteε-Mn4+O2Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
4.DB.15cNsutite(Mn4+,Mn2+)(O,OH)2Hex.
4.DB.15aParamontroseiteV4+O2Orth. mmm (2/m 2/m 2/m)
4.DB.15aRamsdelliteMn4+O2Orth. mmm (2/m 2/m 2/m)
4.DB.20Scrutinyiteα-PbO2Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.25IshikawaiteU4+Fe2+Nb2O8Mon.
4.DB.25Samarskite-(Y)YFe3+Nb2O8Mon. 2/m : P2/b
4.DB.25SrilankiteZrTi2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.25Yttrocolumbite-(Y)Y(U4+,Fe2+)Nb2O8
4.DB.25Calciosamarskite(Ca,U4+)Fe3+(Nb,Ta,Ti)2O8Orth. mmm (2/m 2/m 2/m)
4.DB.25Samarskite-(Yb)YbFe3+(Nb,Ta)2O8Mon. 2/m : P2/b
4.DB.25Ixiolite-(Fe2+)(Ta0.67Fe2+0.33)O2Orth.
4.DB.25Ixiolite-(Mn2+)(Ta0.67Mn2+0.33)O2Orth.
4.DB.30FerberiteFeWO4Mon. 2/m : P2/b
4.DB.30HübneriteMnWO4Mon. 2/m : P2/b
4.DB.30KrasnoselskiteCoWO4Mon.
4.DB.30HeftetjerniteScTaO4Mon. 2/m : P2/b
4.DB.30HuanzalaiteMgWO4Mon. 2/m : P2/b
4.DB.30 vaWolframite Group
4.DB.30Rossovskyite(Fe3+,Ta)(Nb,Ti)O4Mon. 2/m : P2/b
4.DB.35Columbite-(Fe)Fe2+Nb2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Tantalite-(Fe)Fe2+Ta2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Columbite-(Mn)Mn2+Nb2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Tantalite-(Mn)Mn2+Ta2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Columbite-(Mg)(Mg,Fe,Mn)(Nb,Ta)2O6Orth.
4.DB.35Qitianlingite(Fe,Mn)2(Nb,Ta)2WO10Orth. mmm (2/m 2/m 2/m)
4.DB.35Tantalite-(Mg)(Mg,Fe2+)(Ta,Nb)2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.40FerrowodginiteFe2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.40LithiotantiteLiTa3O8Mon. 2/m : P21/b
4.DB.40LithiowodginiteLiTa3O8Mon. 2/m : B2/b
4.DB.40TitanowodginiteMn2+TiTa2O8Mon. 2/m : B2/b
4.DB.40WodginiteMn2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.40FerrotitanowodginiteFe2+TiTa2O8Mon. 2/m : B2/b
4.DB.40Tantalowodginite(Mn2+0.50.5)TaTa2O8Mon. 2/m : B2/b
4.DB.40WolframowodginiteMn(Mn,Sn,Fe,Ta)(W,Ta,Nb)2O8
4.DB.45TivaniteV3+TiO3(OH)Mon. 2/m : P21/b
4.DB.50Carmichaelite(Ti,Cr,Fe)[O2-x(OH)x]Mon. 2/m : P21/b
4.DB.55AlumotantiteAlTaO4Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.60Biehlite((Sb,As)O)2[MoO4]Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for SanmartiniteHide

References for SanmartiniteHide

Reference List:

Localities for SanmartiniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Córdoba Province
    • Minas Department
      • Guasapampa District
Biglia et al. (2016)
  • San Luis Province
    • Chacabuco Department
      • Concarán
Las Especies Minerales De La Republica ... +1 other reference
    • San Martín Department
      • San Martín
Notulae Naturae Academy of Natural Sciences (1948) +1 other reference
Bolivia
 
  • La Paz
    • Sud Yungas Province
      • Yanacachi District
Ahlfeld et al. (1964)
Canada
 
  • Nova Scotia
    • Inverness Co.
Chatterjee (1977)
Mexico
 
  • Sonora
    • Sahuaripa Municipality
Erik Vercammen collection
 
and/or  
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