Minnesotaite
A valid IMA mineral species - grandfathered
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About Minnesotaite
Mahoning-Hull-Rust mine in operation, 2004
Mahoning-Hull-Rust Mine, Hibbing, St. Louis County, Minnesota, USA
Mahoning-Hull-Rust Mine, Hibbing, St. Louis County, Minnesota, USA
Formula:
Fe2+3Si4O10(OH)2
Colour:
Greenish-gray to olive green
Lustre:
Resinous, Waxy, Greasy
Hardness:
1½ - 2
Specific Gravity:
3.01
Crystal System:
Triclinic
Member of:
Name:
For its occurrence in the state of Minnesota.
Unique Identifiers
Mindat ID:
2722
Long-form identifier:
mindat:1:1:2722:5
GUID
(UUID V4):
(UUID V4):
ecfadc51-ec09-45a7-8151-ee63119cf31e
IMA Classification of Minnesotaite
Approved, 'Grandfathered' (first described prior to 1959)
First published:
1944
Classification of Minnesotaite
9.EC.05
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.1.5
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
14.21.9
14 : Silicates not Containing Aluminum
21 : Silicates of Fe and Mg
14 : Silicates not Containing Aluminum
21 : Silicates of Fe and Mg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Mns | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Mns | Siivolam & Schmid (2007) | Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download |
Mns | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Mino | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Mns | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Minnesotaite
Resinous, Waxy, Greasy
Transparency:
Translucent
Comment:
Low luster is common
Colour:
Greenish-gray to olive green
Streak:
White
Hardness:
1½ - 2 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
Micaceous on {001}
Micaceous on {001}
Fracture:
Irregular/Uneven
Comment:
Usually fine-grained
Density:
3.01 g/cm3 (Measured) 2.97 g/cm3 (Calculated)
Optical Data of Minnesotaite
Type:
Biaxial (-)
RI values:
nα = 1.578 - 1.583 nβ = 1.578 - 1.622 nγ = 1.615 - 1.623
2V:
Measured: 4°
Birefringence:
0.037-0.040
Max Birefringence:
δ = 0.037 - 0.040
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v moderate
Pleochroism:
Visible
Comments:
X= pale green
Z= colorless to pale greenish yellow
Z= colorless to pale greenish yellow
Chemistry of Minnesotaite
Mindat Formula:
Fe2+3Si4O10(OH)2
Elements listed:
Common Impurities:
Ti,Al,Mn,Ca,Na,K,H2O
Crystallography of Minnesotaite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.623(2) Å, b = 9.419(2) Å, c = 9.624(3) Å
α = 85.21(3)°, β = 95.64(3)°, γ = 90.00°
α = 85.21(3)°, β = 95.64(3)°, γ = 90.00°
Ratio:
a:b:c = 0.597 : 1 : 1.022
Unit Cell V:
505.46 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Usually fine-grained dense masses of microscopic plates or needles
Twinning:
Inferred from single crystal X-ray analysis
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
9.54 Å | (100) |
4.78 Å | (20) |
3.18 Å | (50) |
2.76 Å | (30) |
2.66 Å | (40) |
2.54 Å | (30) |
2.53 Å | (50) |
2.21 Å | (20) |
Comments:
2.54 and 2.53 frequently overlap; 41-594
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 5: Initiation of plate tectonics | <3.5-2.5 |
40 : Regional metamorphism (greenschist, amphibolite, granulite facies) |
Geological Setting:
Low grade metamorphosed banded iron formations; also hydrothermal alteration around sulphide veins.
Type Occurrence of Minnesotaite
Co-Type Localities:
Geological Setting of Type Material:
Banded Iron Formation
Reference:
Gruner, J.W. (1944) The composition and structure of minnesotaite, a common iron silicate in iron formations. American Mineralogist: 29: 363-372.
Synonyms of Minnesotaite
Other Language Names for Minnesotaite
Relationship of Minnesotaite to other Species
Member of:
Other Members of this group:
Ferripyrophyllite | Fe3+Si2O5(OH) | Mon. 2/m |
Pyrophyllite | Al2Si4O10(OH)2 | Tric. 1 |
Talc | Mg3Si4O10(OH)2 | Tric. 1 : P1 |
Willemseite | Ni3Si4O10(OH)2 | Mon. |
Common Associates
Related Minerals - Strunz-mindat Grouping
9.EC. | Balestraite | KLi2V5+Si4O12 |
9.EC. | Meifuite | KFe6(Si7Al)O19(OH)4Cl2 |
9.EC.05 | Talc | Mg3Si4O10(OH)2 |
9.EC.05 | Willemseite | Ni3Si4O10(OH)2 |
9.EC.9.EC. | Voloshinite | Rb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2 |
9.EC.10 | Ferripyrophyllite | Fe3+Si2O5(OH) |
9.EC.10 | Pyrophyllite | Al2Si4O10(OH)2 |
9.EC.10 | Luanshiweiite | KLiAl1.5(Si3.5Al0.5)O10(OH)2 |
9.EC.10 | Fluorluanshiweiite | KLiAl1.5(Si3.5Al0.5)O10F2 |
9.EC.10 | Manganiceladonite | K(MgMn3+◻)(Si4O10)(OH)2 |
9.EC.10 | Garmite | CsLiMg2(Si4O10)F2 |
9.EC.10 | Gorbunovite | CsLi2(Ti,Fe)Si4O10(F,OH,O)2 |
9.EC.15 | Boromuscovite | KAl2(BSi3O10)(OH)2 |
9.EC.15 | Celadonite | K(MgFe3+◻)(Si4O10)(OH)2 |
9.EC.15 | Chernykhite | (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 |
9.EC.15 | Montdorite | (K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4 |
9.EC.15 | Muscovite | KAl2(AlSi3O10)(OH)2 |
9.EC.15 | Nanpingite | CsAl2(AlSi3O10)(OH,F)2 |
9.EC.15 | Paragonite | NaAl2(AlSi3O10)(OH)2 |
9.EC.15 | Roscoelite | K(V3+,Al)2(AlSi3O10)(OH)2 |
9.EC.15 | Tobelite | (NH4,K)Al2(AlSi3O10)(OH)2 |
9.EC.15 | Aluminoceladonite | K(MgAl◻)(Si4O10)(OH)2 |
9.EC.15 | Chromphyllite | K(Cr,Al)2(AlSi3O10)(OH,F)2 |
9.EC.15 | Ferroaluminoceladonite | K(Fe2+Al◻)(Si4O10)(OH)2 |
9.EC.15 | Ferroceladonite | K(Fe2+Fe3+◻)(Si4O10)(OH)2 |
9.EC.15 | Chromceladonite | K(MgCr◻)(Si4O10)(OH)2 |
9.EC.15 | Tainiolite | KLiMg2(Si4O10)F2 |
9.EC.15 | Ganterite | (Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2 |
9.EC.15 | UM1988-22-SiO:AlCaFFeHKLiMg | KLiMgAl2Si3O10F2 |
9.EC.15 | Kreiterite | CsLi2Fe3+(Si4O10)F2 |
9.EC.20 | Annite | KFe2+3(AlSi3O10)(OH)2 |
9.EC.20 | Ephesite | NaLiAl2(Al2Si2O10)(OH)2 |
9.EC.20 | Hendricksite | KZn3(Si3Al)O10(OH)2 |
9.EC.20 | Masutomilite | (K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2 |
9.EC.20 | Norrishite | KLiMn3+2(Si4O10)O2 |
9.EC.20 | Phlogopite | KMg3(AlSi3O10)(OH)2 |
9.EC.20 | Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
9.EC.20 | Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 |
9.EC.20 | Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 |
9.EC.20 | Tetraferriphlogopite | KMg3(Fe3+Si3O10)(OH,F)2 |
9.EC.20 | Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 |
9.EC.20 | Wonesite | (Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4 |
9.EC.20 | Eastonite | KMg2Al(Al2Si2O10)(OH)2 |
9.EC.20 | Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 |
9.EC.20 | Trilithionite | K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 |
9.EC.20 | Fluorannite | KFe2+3(Si3Al)O10F2 |
9.EC.20 | Shirokshinite | K(NaMg2)(Si4O10)F2 |
9.EC.20 | Shirozulite | KMn2+3(Si3Al)O10(OH)2 |
9.EC.20 | Sokolovaite | CsLi2Al(Si4O10)F2 |
9.EC.20 | Aspidolite | NaMg3(AlSi3O10)(OH)2 |
9.EC.20 | Fluorophlogopite | KMg3(Si3Al)O10F2 |
9.EC.20 | UM2004-49-SiO:AlCsFHKLi | (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2 |
9.EC.20 | Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 |
9.EC.20 | Yangzhumingite | KMg2.5(Si4O10)F2 |
9.EC.20 | Orlovite | KLi2Ti(Si4O10)OF |
9.EC.20 | Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 |
9.EC.20 | Chloroferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2 |
9.EC.22 | Pimelite | Ni3Si4O10(OH)2 · 4H2O |
9.EC.30 | Chlorophaeite | (Ca,Mg,Fe)2Fe2Si4O13 · 10H2O |
9.EC.30 | Margarite | CaAl2(Al2Si2O10)(OH)2 |
9.EC.35 | Anandite | (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 |
9.EC.35 | Bityite | CaLiAl2(AlBeSi2O10)(OH)2 |
9.EC.35 | Clintonite | CaAlMg2(SiAl3O10)(OH)2 |
9.EC.35 | Kinoshitalite | (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 |
9.EC.35 | Ferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 |
9.EC.35 | Oxykinoshitalite | (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 |
9.EC.35 | Fluorokinoshitalite | BaMg3(Al2Si2O10)F2 |
9.EC.40 | Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O |
9.EC.40 | Kurumsakite | (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) |
9.EC.40 | Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O |
9.EC.40 | Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O |
9.EC.40 | Volkonskoite | Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O |
9.EC.40 | Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O |
9.EC.45 | Hectorite | Na0.3(Mg,Li)3(Si4O10)(F,OH)2 |
9.EC.45 | Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O |
9.EC.45 | Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O |
9.EC.45 | Spadaite | MgSiO2(OH)2 · H2O (?) |
9.EC.45 | Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 |
9.EC.45 | Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O |
9.EC.45 | Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) |
9.EC.45 | Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O |
9.EC.45 | Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
9.EC.50 | Vermiculite | Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O |
9.EC.52 | Tarasovite | near NaKAl11Si13O40(OH)9 · 3H2O |
9.EC.55 | Baileychlore | (Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8 |
9.EC.55 | Chamosite | (Fe2+)5Al(Si,Al)4O10(OH,O)8 |
9.EC.55 | Clinochlore | Mg5Al(AlSi3O10)(OH)8 |
9.EC.55 | Cookeite | (LiAl4◻)[AlSi3O10](OH)8 |
9.EC.55 | Franklinfurnaceite | Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 |
9.EC.55 | Gonyerite | (Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8 |
9.EC.55 | Nimite | (Ni,Mg,Al)6((Si,Al)4O10)(OH)8 |
9.EC.55 | Orthochamosite | (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8 |
9.EC.55 | Pennantite | Mn2+5Al(AlSi3O10)(OH)8 |
9.EC.55 | Sudoite | Mg2Al3(Si3Al)O10)(OH)8 |
9.EC.55 | Donbassite | Al4.33(Si3Al)O10(OH)8 |
9.EC.55 | Glagolevite | Na(Mg,Al)6(AlSi3O10)(OH,O)8 |
9.EC.55 | Borocookeite | (LiAl4◻)[BSi3O10](OH)8 |
9.EC.60 | Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O |
9.EC.60 | Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O |
9.EC.60 | Dozyite | Mg7Al2(Al2Si4O15)(OH)12 |
9.EC.60 | Hydrobiotite | K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O |
9.EC.60 | Karpinskite | (Ni,Mg)2Si2O5(OH)2 (?) |
9.EC.60 | Kulkeite | Mg8Al(AlSi7O20)(OH)10 |
9.EC.60 | Lunijianlaite | Li0.7Al6.2(AlSi7O20)(OH,O)10 |
9.EC.60 | Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
9.EC.60 | Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 |
9.EC.60 | Tosudite | Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O |
9.EC.60 | Brinrobertsite | Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O |
9.EC.65 | Macaulayite | (Fe,Al)24Si4O43(OH)2 |
9.EC.70 | Burckhardtite | Pb2(Fe3+Te6+)[AlSi3O8]O6 |
9.EC.75 | Ferrisurite | (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O |
9.EC.75 | Surite | (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 |
9.EC.75 | Niksergievite | (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O |
9.EC.80 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 |
Fluorescence of Minnesotaite
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Minnesotaite
mindat.org URL:
https://www.mindat.org/min-2722.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Minnesotaite
Reference List:
Localities for Minnesotaite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Skirrow (1993) |
| www.earth2006.org.au (n.d.) |
| Barley et al. (1999) |
| Grubb (1971) |
| Gole (1980) |
| Angerer et al. (2022) |
| Lascelles (2006) |
| Lascelles (2006) |
Belarus | |
| Levitskiy et al. (2018, July) |
Brazil | |
| Huang et al. (2022) |
Grainger et al. (2008) | |
Canada | |
| Handbook of Mineralogy. +2 other references |
| Klein et al. (1976) |
| Fyon (1986) |
| Econ Geol. (1995) +1 other reference |
| Guggenheim et al. (1986) |
Lesher (1978) +1 other reference | |
Guggenheim et al. (1986) | |
Klein et al. (1976) | |
China | |
| Feng Xiancan et al. (1986) |
| Jinchu Zhu and Fusheng Zhang (1987) |
| Hongbing Hao and Wei Zhang (2001) |
Czech Republic | |
| Fuksová (2010) |
Finland | |
| Paakkola (1971) |
India | |
| Saravanan et al. (2009) |
Ireland | |
| Schultz (1966) +2 other references |
Italy | |
| Nisio et al. (1987) |
| Stara et al. (1999) |
Romania | |
Hîrtopanu et al. (2003) +1 other reference | |
| minerals-of-the-carpathians.eu (2008) |
| Hîrtopanu (1997) +1 other reference |
Russia | |
| Kazachenko et al. (2013) |
South Africa | |
| Hammond et al. (2006) |
| Cairncross et al. (1995) |
Spain | |
| Gaines et al. (1997) |
Sweden | |
| Baker (1985) |
Tanzania | |
| Kühn (2009) |
UK | |
| Handbook of Mineralogy. +2 other references |
Ukraine | |
| Sharygin et al. (2014) |
USA | |
| Rocks & Min.: 63:108. |
| Bozhilov et al. (2001) |
| Heinrich et al. (2004) |
... | |
... | |
| Morris Jr. (1983) |
| Morris Jr. (1983) |
| - (2005) |
| Jay Ellis Ransom |
| Blake (1965) +1 other reference |
USGS Prof Paper 407 | |
| Blake (1965) +1 other reference |
Morey et al. (1993) | |
| - (2005) |
- (2005) | |
| Guggenheim et al. (1983) |
| Can Mineral September 1986 v. 24 no. 3 ... |
| Am Min 29:363-372 |
- (2005) | |
Erik Vercammen collection | |
- (2005) | |
55TH INSTITUTE ON LAKE SUPERIOR GEOLOGY (2009) | |
- (2005) | |
- (2005) | |
- (2005) | |
- (2005) | |
- (2005) | |
- (2005) | |
55TH INSTITUTE ON LAKE SUPERIOR GEOLOGY (2009) | |
- (2005) | |
- (2005) | |
- (2005) | |
| NMBMMR Memoir 38 Geology and Technology ... |
| Can Mineral February 1998 v. 36 no. 1 ... +2 other references |
| Cordua (1998) |
| Cordua (1998) |
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Bluebell Mine, Riondel, Slocan Mining Division, British Columbia, Canada